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Description of BS EN ISO 21068-1:2024 2024This document gives definitions and specifies techniques for the preparation of samples for the chemical analysis of silicon-carbide-containing raw materials and refractory products including: a)      SiC raw materials; b)      graphite brick containing silicon carbide; c)       silicon carbide brick (includes the bricks containing silicon nitride, silicon oxynitride, sialon); d)      refractories containing carbon and/or silicon carbide mixed with clay; e)      refractories containing carbon and/or silicon carbide mixed with silica (and fused silica); f)        refractories containing carbon and/or silicon carbide mixed with high alumina material; g)      refractories containing carbon and/or silicon carbide mixed with magnesia (and dolomite); h)      refractories containing carbon and/or silicon carbide mixed with chrome mineral or magnesia-chrome materials; i)        refractories containing carbon and/or silicon carbide except those described in a) to h) above. The items of analysis described in ISO 21068-2, ISO 21068-3 and ISO 21068-4 are as follows: —    loss on drying (LOD); —    loss on ignition (LOI); —    total carbon, Ctotal; —    free carbon, Cfree; —    silicon carbide, SiC; —    free silicon (Sifree); —    free aluminium (Alfree); —    free magnesium (Mgfree); —    free iron (Fefree); —    silicon(IV) dioxide (SiO2); —    aluminium(III) oxide (Al2O3); —    iron(III) oxide (Fe2O3); —    titanium(IV) oxide (TiO2); —    calcium oxide (CaO); —    magnesium oxide (MgO); —    sodium oxide (Na2O); —    potassium oxide (K2O); —    chromium(III) oxide (Cr2O3); —    zirconium(IV) oxide (ZrO2); —    boron oxide (total boron calculated as B2O3); —    nitrogen; —    oxygen; —    nitrides (undifferentiated: Si3N4, AlN, BN, sialon, oxy-nitrides, etc.); —    mineralogical phases (XRD-methods).
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