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Description of ASTM-D5769 2020ASTM D5769-20Historical Standard: Standard Test Method for Determination of Benzene, Toluene, and Total Aromatics in Finished Gasolines by Gas Chromatography/Mass SpectrometryASTM D5769Scope 1.1 This test method covers the determination of benzene, toluene, other specified individual aromatic compounds, and total aromatics in finished motor gasoline, including gasolines containing oxygenated blending components, by gas chromatography/mass spectrometry (GC/MS). 1.2 This test method has been tested for the following concentration ranges, in liquid volume percent, for the following aromatics: benzene, 0.1 % to 4 %; toluene, 1 % to 13 %; and total (C6 to C12) aromatics, 10 % to 42 %. The round-robin study did not test the method for individual hydrocarbon process streams in a refinery, such as reformates, fluid catalytic cracked naphthas, and so forth, used in the blending of gasolines. 1.3 Results are reported to the nearest 0.01 % for benzene and 0.1 % for the other aromatics by liquid volume. 1.4 This test method includes a relative bias section for EPA spark-ignition engine fuel benzene regulations reporting based on Practice D6708 accuracy assessment between Test Method D5769 and Test Method D3606 as a possible Test Method D5769 alternative to Test Method D3606. The Practice D6708 derived correlation equation is only applicable for blended fuels in the benzene concentration range from 0.0 % to 2.50 % by volume as measured by Test Method D5769. The applicable Test Method D3606 range for benzene is from 0.0 % to 2.47 % by volume as reported by Test Method D3606. 1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to its use. 1.7 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee. Keywords aromatics; benzene; gas chromatography; gasolines; GC/MS; mass spectrometry; toluene; ICS Code ICS Number Code 75.160.20 (Liquid fuels) DOI: 10.1520/D5769-20 The following editions for this book are also available...
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About ASTMASTM International, formerly known as the American Society for Testing and Materials (ASTM), is a globally recognized leader in the development and delivery of international voluntary consensus standards. Today, some 12,000 ASTM standards are used around the world to improve product quality, enhance safety, facilitate market access and trade, and build consumer confidence. ASTM’s leadership in international standards development is driven by the contributions of its members: more than 30,000 of the world’s top technical experts and business professionals representing 150 countries. Working in an open and transparent process and using ASTM’s advanced electronic infrastructure, ASTM members deliver the test methods, specifications, guides, and practices that support industries and governments worldwide. |
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