ASTM D5315-92(1998)
Historical Standard: ASTM D5315-92(1998) Standard Test Method for N-Methyl-Carbamoyloximes and N-Methylcarbamates in Water by Direct Aqueous Injection HPLC with Post-Column Derivatization
SUPERSEDED (see Active link, below)
ASTM D5315
1. Scope
1.1 This is a high-performance liquid chromatographic (HPLC) test method applicable to the determination of certain n-methylcarbamoyloximes and n-methylcarbamates in ground water and finished drinking water (1) (also see EPA Method 531.1, Revision 3.0). The following compounds can be determined using this test method:
Chemical Abstract Services Analyte Registry Number A Aldicarb 116-06-3 Aldicarb sulfone 1646-88-4 Aldicarb sulfoxide 1646-87-3 Baygon 114-26-1 Carbaryl 63-25-2 Carbofuran 1563-66-2 3-Hydroxycarbofuran 16655-82-6 Methiocarb 2032-65-7 Methomyl 16752-77-5 Oxamyl 23135-22-0 A Numbering system of Chemical Abstracts, Inc.1.2 This test method has been validated in a collaborative round-robin study (2) and estimated detection limits (EDLs) have been determined for the analytes listed in 1.1 (Table 1). Observed detection limits may vary between ground waters, depending on the nature of interferences in the sample matrix and the specific instrumentation used.
1.3 This test method is restricted to use by, or under the supervision of, analysts experienced in both the use of liquid chromatography and the interpretation of liquid chromatograms. Each analyst should demonstrate an ability to generate acceptable results with this test method using the procedure described in 12.3.
1.4 When this test method is used to analyze unfamiliar samples for any or all of the analytes listed in 1.1, analyte identifications should be confirmed by at least one additional qualitative technique.
1.5 The values stated in SI units are to be regarded as the standard.
1.6 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Notes 1 and 3. Additional guidance on laboratory safety is available and suitable references for the information are provided (3-5).
2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.
ASTM Standards
D1129 Terminology Relating to Water
D1192 Guide for Equipment for Sampling Water and Steam in Closed Conduits
D1193 Specification for Reagent Water
D2777 Practice for Determination of Precision and Bias of Applicable Test Methods of Committee D19 on Water
D3370 Practices for Sampling Water from Closed Conduits
D3694 Practices for Preparation of Sample Containers and for Preservation of Organic Constituents
E682 Practice for Liquid Chromatography Terms and Relationships
U.S. Environmental Protection Agency Standard
EPAMethod531.2, Revision 1.0, USEPA, EMSL-Cincinnati, 2001 Published by the U.S. Environmental Protection Agency, Environmental Monitoring and Support Laboratory, Cincinnati, OH 45268, 2001.Keywords
carbamates; direct aqueous injection; drinking water; HPLC; N-methylcarbamates; N-methylcarbamoyloximes; Carbamates; Direct aqueous injection; Drinking water; Ground water; Herbicides; HPLC (high performance liquid chromatography); Insecticides; Laboratory water testing; Liquid chromatography (LC)--water analysis; n -Methylcarbamates; n -Methylcarbamoyloximes; Organic compounds--water; Post-column derivatization
ICS Code
ICS Number Code 71.080.30 (Organic nitrogen compounds)
DOI: 10.1520/D5315-92R98
ASTM International is a member of CrossRef.
