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Significance and Use

This test method provides rapid and precise measurement of total sulfur in petroleum and petroleum products with a minimum of sample preparation. A typical analysis time is 1 to 2 minutes per sample.

The quality of many petroleum products is related to the amount of sulfur present. Knowledge of sulfur concentration is necessary for processing purposes. There are also regulations promulgated in federal, state, and local agencies that restrict the amount of sulfur present in some fuels.

This test method provides a means of determining whether the sulfur content of petroleum or a petroleum product meets specification or regulatory limits.

When this test method is applied to petroleum materials with matrices significantly different from the white oil calibration materials specified in this test method, the cautions and recommendations in Section 5 should be observed when interpreting results.

Note 2The equipment specified for Test Method D2622 tends to be more expensive than that required for alternative test methods, such as Test Method D4294 . Consult the Index to ASTM Standards for alternative test methods.

1. Scope

1.1 This test method covers the determination of total sulfur in petroleum and petroleum products that are single-phase and either liquid at ambient conditions, liquefiable with moderate heat, or soluble in hydrocarbon solvents. These materials can include diesel fuel, jet fuel, kerosene, other distillate oil, naphtha, residual oil, lubricating base oil, hydraulic oil, crude oil, unleaded gasoline, gasohol and biodiesel.

1.2 The range of this test method is between the PLOQ value (calculated by procedures consistent with Practice D6259 ) of 3 mg/kg total sulfur and the highest level sample in the round robin, 4.6 wt. % total sulfur.

Note 1Instrumentation covered by this test method can vary in sensitivity. The applicability of the test method at sulfur concentrations below 3 mg/kg may be determined on an individual basis for WDXRF instruments capable of measuring lower levels, but precision in this test method does not apply.

1.2.1 The values of the limit of quantitation (LOQ) and method precision for a specific laboratory s instrument depends on instrument source power (low or high power), sample type, and the practices established by the laboratory to perform the method.

1.3 Samples containing more than 4.6 mass % sulfur should be diluted to bring the sulfur concentration of the diluted material within the scope of this test method. Samples that are diluted can have higher errors than indicated in Section 14 than non-diluted samples.

1.4 Volatile samples (such as high vapor pressure gasolines or light hydrocarbons) may not meet the stated precision because of selective loss of light materials during the analysis.

1.5 A fundamental assumption in this test method is that the standard and sample matrices are well matched, or that the matrix differences are accounted for (see 12.2). Matrix mismatch can be caused by C/H ratio differences between samples and standards or by the presence of other interfering heteroatoms or species (see Table 1).

1.6 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

2. Referenced Documents (purchase separately) The documents listed below are referenced within the subject standard but are not provided as part of the standard.

ASTM Standards

D4057 Practice for Manual Sampling of Petroleum and Petroleum Products

D4177 Practice for Automatic Sampling of Petroleum and Petroleum Products

D4294 Test Method for Sulfur in Petroleum and Petroleum Products by Energy Dispersive X-ray Fluorescence Spectrometry

D4927 Test Methods for Elemental Analysis of Lubricant and Additive Components--Barium, Calcium, Phosphorus, Sulfur, and Zinc by Wavelength-Dispersive X-Ray Fluorescence Spectroscopy

D6259 Practice for Determination of a Pooled Limit of Quantitation

D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance

D7343 Practice for Optimization, Sample Handling, Calibration, and Validation of X-ray Fluorescence Spectrometry Methods for Elemental Analysis of Petroleum Products and Lubricants

E29 Practice for Using Significant Digits in Test Data to Determine Conformance with Specifications

Keywords

analysis; diesel; gasoline; jet fuel; kerosene; petroleum; spectrometry; sulfur; wavelength dispersive x-ray fluorescence; X-ray; Petroleum products (liquid); Fuel oils; Spectroscopy--X-ray fluorescence (XRF); Fuel sulfur; X-ray spectrometry; XRF (X-ray fluorescence)--petroleum products;

ICS Code

ICS Number Code 75.080 (Petroleum products in general)

DOI: 10.1520/D2622-10

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ASTM D2622