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BS EN 71-3:2013+A3:2018 Safety of toys - Migration of certain elements, 2018
- undefined
- 1 Scope
- 2 Normative references
- 3 Terms and definitions
- 4 Requirements [Go to Page]
- 4.1 Toy material categories (see H.4)
- 4.2 Specific requirements
- 5 Principle
- 6 Reagents and apparatus [Go to Page]
- 6.1 Reagents
- 6.2 Apparatus
- 7 Sampling and sample preparation [Go to Page]
- 7.1 Selection of test portions
- 7.2 Standards preparation
- 7.3 Sample preparation [Go to Page]
- 7.3.1 General
- 7.3.2 Category I: Dry, brittle, powder like or pliable and Category II: Liquid or sticky
- 7.3.3 Category III: Scraped-off [Go to Page]
- 7.3.3.1 Coatings of paint, varnish, lacquer, printing ink, polymer and similar coatings
- 7.3.3.2 Polymeric and similar materials including laminates and reinforced textiles, but excluding other textiles
- 7.3.3.3 Paper and paper board
- 7.3.3.4 Textiles, whether natural or synthetic (see H.7)
- 7.3.3.5 Glass, ceramic and metallic materials
- 7.3.3.6 Other materials, whether mass coloured or not
- 7.4 Migration procedure [Go to Page]
- 7.4.1 General
- 7.4.2 Category I: Dry, brittle, powder like or pliable and Category II: Liquid or sticky [Go to Page]
- 7.4.2.1 Samples containing grease, oil, wax or similar material
- 7.4.2.2 Samples not containing grease, oil, wax or similar material
- 7.4.3 Category III: Scraped-off [Go to Page]
- 7.4.3.1 Coatings of paint, varnish, lacquer, printing ink, polymer and similar coatings
- 7.4.3.2 Polymeric and similar materials including laminates and reinforced textile, but excluding other textiles
- 7.4.3.3 Paper and paper board
- 7.4.3.4 Textiles, whether natural or synthetic
- 7.4.3.5 Glass, ceramic and metallic materials
- 7.4.3.6 Other materials, whether mass coloured or not
- 8 Methods of analysis
- 9 Calculation of results [Go to Page]
- 9.1 General elements [Go to Page]
- 9.1.1 Calibration curve
- 9.1.2 Calculation of migration
- 9.1.3 Interpretation of results
- 9.2 Chromium (III) and Chromium (VI) [Go to Page]
- 9.2.1 Calibration curve
- 9.2.2 Calculation of migration
- 9.2.3 Interpretation of results
- 9.3 Organic tin [Go to Page]
- 9.3.1 Calibration curves
- 9.3.2 Calculation of migration of single organic tin compound
- 9.3.3 Calculation of migration of organic tin
- 9.3.4 Interpretation of results
- 10 Test report
- Annex A (informative)Significant technical changes between this European Standard and the previous version
- Annex B (informative)Method performance [Go to Page]
- B.1 Method performance
- B.2 Use of measurement uncertainty in compliance assessment
- B.3 Information on round robin test
- Annex C (normative)Sieve requirements
- Annex D (informative)Preparation and analysis of test portion
- Annex E (informative)Method of analysis for general elements [Go to Page]
- E.1 Principle
- E.2 Working solutions [Go to Page]
- E.2.1 Working solutions ICP-MS [Go to Page]
- E.2.1.1 Stock solution (M1)
- E.2.1.2 Diluted stock solution (M2)
- E.2.1.3 Working solutions
- E.2.1.4 Internal Standard stock solution
- E.2.2 Working solutions ICP-OES [Go to Page]
- E.2.2.1 Stock solution (M1)
- E.2.2.2 Working solutions (calibration standards)
- E.3 Procedure
- E.4 Analysis [Go to Page]
- E.4.1 General
- E.4.2 Limit of detection and quantification
- Annex F (informative)Methods of analysis for speciation of Chromium (III) and (VI) [Go to Page]
- F.1 Principle
- F.2 Reagents
- F.3 Apparatus
- F.4 Procedure
- F.5 Analysis [Go to Page]
- F.5.1 General
- F.5.2 LC-ICP-MS conditions
- F.5.3 Limit of detection and quantification [Go to Page]
- F.5.3.1 General
- F.5.3.2 Example of chromatogram
- Annex G (informative)Method of analysis for organic tin (see H.10) [Go to Page]
- G.1 Principle
- G.2 Terms and definitions
- G.3 Reagents
- G.4 Apparatus
- G.5 Procedure [Go to Page]
- G.5.1 Sample derivatisation
- G.5.2 Calibration standards
- G.6 Analysis [Go to Page]
- G.6.1 General
- G.6.2 Example of GC conditions
- G.6.3 Example of MS conditions
- G.6.4 Limit of detection and quantification
- G.6.5 Example of a GC-MS chromatogram
- Annex H (informative)Rationale [Go to Page]
- H.1 General
- H.2 Mouthing behaviour of children (Scope)
- H.3 Skin contact (Scope)
- H.4 Toy categories (4.1)
- H.5 Test portions (7.1, 7.3.3.2, 7.3.3.3, 7.3.3.6)
- H.6 Size of test pieces (7.3.3.2, 7.3.3.3, 7.3.3.4)
- H.7 Textile threads
- H.8 Chromium (VI) migration (7.4)
- H.9 Filtration of migration solutions (7.4.2.1, 7.4.2.2, 7.4.3.1, 7.4.3.3, 7.4.3.5)
- H.10 Organic tin (9.3)
- H.11 pH value
- H.12 De-waxing (see 7.3.2)
- Annex I (informative)Conformity assessment [Go to Page]
- I.1 General
- I.2 Chromium VI
- Annex J (informative)List of other organic tin compounds
- Annex ZA (informative)Relationship between this European Standard and the Essential Requirements of EU Directive 2009/48/EC aimed to be covered [Go to Page]